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Silver High Energy Auger Transitions

 

作者: R. Landers,   S. G. C. de Castro,   G. G. Kleiman,  

 

期刊: Surface Science Spectra  (AIP Available online 1993)
卷期: Volume 2, issue 3  

页码: 177-183

 

ISSN:1055-5269

 

年代: 1993

 

DOI:10.1116/1.1247697

 

出版商: American Vacuum Society

 

关键词: SILVER;AES;X RADIATION;VALENCE BANDS;POLYCRYSTALS;FOILS;HIGH−RESOLUTION METHODS;SPUTTERING

 

数据来源: AIP

 

摘要:

The data presented correspond to theLMMandLMNAuger transitions of silver (some of theLMNtransitions involve valence electrons). Differences in screening are clearly seen by the large change in Auger parameter on going fromLMMtoLMN[see R. Landers, P. A. P. Nascente, S. G. C. de Castro, and G. G. Kleiman, J. Phys. Condens. Matter4, 5881 (1992); Surf. Sci.287, 802 (1993)]. Analysis of theLMMdata tends to indicate the absence of Coster–Kroning decay from theL2toL3initial states, butL1–L2,3cannot be ruled out [see G. G. Kleiman, R. Landers, and S. G. C. de Castro, J. Electron. Spectrosc. (to be published)]. The relatively poor resolution (2.5 eV FWHM for Au 4f) does not seem to have degraded the spectra appreciably since spectra of the more intenseL3M4,5M4,5line taken with higher resolution (1.5 eV FWHM Au 4f) did not show any additional features. The absolute energy accuracy is probably around ± 1 eV but is difficult to quantify for lack of accurate literature data.

 

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