Structural and optical properties of hydrogenated amorphous silicon carbide deposited by glow discharge from C3H8‐SiH4‐H2mixture
作者:
Jang‐Ho Park,
Hyuk‐Sang Kwon,
Jai‐Young Lee,
期刊:
Journal of Applied Physics
(AIP Available online 1992)
卷期:
Volume 72,
issue 11
页码: 5246-5252
ISSN:0021-8979
年代: 1992
DOI:10.1063/1.352007
出版商: AIP
数据来源: AIP
摘要:
Films of hydrogenated amorphous silicon carbide (a‐SiC:H) have been prepared by a glow discharge decomposition from gas mixtures of C3H8‐SiH4‐H2and CH4‐SiH4‐H2, in order to examine the effect of hydrocarbon gases on the structural and optical properties of these films. To study the influence of hydrogen on those properties of the propane‐based films, the properties of the films deposited at different substrate temperatures (Ts) are systematically investigated using infrared (IR) and ultraviolet‐visible absorption spectroscopies. By observing the change of intensities of IR absorption peaks with substrate temperature, the hydrogen bonding responsible for the absorption peaks could be assigned more accurately. WhenTsis increased up to 300 °C, intensities of CH3and SiH2groups are reduced, indicating the formation of a dense network structure. At the same carbon concentration in gas mixtures, propane allows more carbon and hydrogen atoms to be effectively incorporated into the film than methane. The IR spectra reveal that the structure of a propane‐based film has the characteristics of that of two kinds of films, methane‐ and ethylene‐based films. It is found that the chemical bonding nature of the hydrocarbon gas strongly affects the bonding structure and the composition of the films. From these results, it is proposed that the use of propane is suitable for the fabrication of high‐qualitya‐SiC:H with a wide optical gap (≳2.0 eV) and a deposition rate of ∼2 A˚/s.
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