Reversibly Photo-Induced Phase Transition in Single Crystals of Polydiacititlenes
作者:
Shin-Ya Koshihara,
Yoshinori Tokura,
Takao Koda,
Kenji Takeda,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1992)
卷期:
Volume 218,
issue 1
页码: 43-48
ISSN:1058-725X
年代: 1992
DOI:10.1080/10587259208047013
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
We have observed novel photo-induced phenomena in conjugated polymers; the reversibly photo-induced phase transitions in single crystals of poly-diacetylene(PDA). Dependence of the phase conversion efficiency on excitation photon energy shows that the photo-generation of charge-carriers (polarons), not excitons, is responsible for the macroscopic phase change.
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