Cationic Copolymerization of Epichlorohydrin with Styrene Oxide and with Cyclohexene Oxide
作者:
W.M. Pasika,
DianJia Chen,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1991)
卷期:
Volume 28,
issue 5-6
页码: 545-555
ISSN:0022-233X
年代: 1991
DOI:10.1080/00222339108052106
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Cationic copolymerizations of epichlorohydrin (ECH) (chloro-methyl oxirane) with styrene oxide (SO) (phenyl oxirane) and with 1,2-cyclohexene oxide (CO) (7-oxabicyclo [410] heptane) were carried out at 50°C by employing the salt triphenylmethyl hexachloro-antimonate (HC) (Ph3CSbCl6) as initiator. NMR spectra before and after attempted extractions of the polymeric products indicated that the resulting polymeric products were true copolymers and not mixtures of the respective homopolymers. Monomer reactivity ratios for both pairs of comonomers were determined; for one pair the values werer1(ECH) = 3.29,r2(CO) = 0.16 and for the second pairr1(ECH) = 0.57,r2(SO) = 0.16.
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