首页   按字顺浏览 期刊浏览 卷期浏览 On the Role of the High-Spin State in the Water Exchange Reaction of Hexaaquocobalt(III)
On the Role of the High-Spin State in the Water Exchange Reaction of Hexaaquocobalt(III)

 

作者: JayR. Winkler,   StevenF. Rice,   HarryB. Gray,  

 

期刊: Comments on Inorganic Chemistry  （Taylor Available online 1981）
卷期: Volume 1, issue 1  

页码: 47-51

 

ISSN:0260-3594

 

年代: 1981

 

DOI:10.1080/02603598108078079

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The potential surface for the5T2gstate of Co(OH2)3+6, as estimated from spectroscopic data plus some assumptions from the work of Wilson and Solomon on Co(NH3)3+6, has a minimum that falls about 4 kcal mol−1above the low-spin ground state. The quintet state probably plays a role in the substitutional lability of the aquo ion, as suggested 30 years ago by Taube and coworkers.

 

点击下载:  PDF (182KB)



返 回