首页   按字顺浏览 期刊浏览 卷期浏览 Gel permeation chromatography of polymers: Use of unperturbed dimensions for calibration
Gel permeation chromatography of polymers: Use of unperturbed dimensions for calibration

 

作者: J.V. Dawkins,  

 

期刊: Journal of Macromolecular Science, Part B  (Taylor Available online 1968)
卷期: Volume 2, issue 4  

页码: 623-639

 

ISSN:0022-2348

 

年代: 1968

 

DOI:10.1080/00222346808212462

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Experimental GPC calibration data for polystyrene, poly(methyl methacrylate), and poly(dimethyl siloxane) in chloroform is reported. These polymers have similar hydrodynamic volumes, since their unperturbed dimensions and extensions in chloroform, due to polymersolvent interaction, are very similar. As a result, the same molecular weight calibration curve is obtained for the three polymers. Recently published GPC data is examined on a plot of logarithm of unperturbed end-to-end distance against elution volume. This procedure gives a universal calibration for linear polymer molecules, providing the column combination, solvent, and temperature do not change. For the data of Meyerhoff, use of the unperturbed dimensions is superior to the plot of η suggested by Grubisic, Rempp, and Benoit. A possible explanation, based on a model for the polystyrene gel pores, is proposed for the use of the unperturbed dimensions.

 

点击下载:  PDF (621KB)



返 回