Perturbation of Moist CO Oxidation by Trace Quantities of CH3Cl
作者:
J. F. ROESLER,
R. A. YETTER,
F. L. DRYER,
期刊:
Combustion Science and Technology
(Taylor Available online 1994)
卷期:
Volume 101,
issue 1-6
页码: 199-229
ISSN:0010-2202
年代: 1994
DOI:10.1080/00102209408951873
出版商: Taylor & Francis Group
关键词: Chlorinated hydrocarbons;incineration;moist CO oxidation;kinetic modeling
数据来源: Taylor
摘要:
The final destruction of toxic waste in incinerators occurs in the post flame region. The controlling chemistry in this region may be described as that of fuel-lean oxidation of CO in the presence of H2O and HCl perturbed by trace quantities of chlorinated hydrocarbons. In the present study, a reaction bath with initially about 1% of CO, O2, and H2O in nitrogen was perturbed by CH3Cl in a turbulent flow reactor operating at atmospheric pressure, with temperatures between 1000 and 1150 K. The equivalence ratio ranged from 0.25 to 1.0 and the initial CH3Cl ranged from 0 to 250ppm.
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