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Perturbation of Moist CO Oxidation by Trace Quantities of CH3Cl

 

作者: J. F. ROESLER,   R. A. YETTER,   F. L. DRYER,  

 

期刊: Combustion Science and Technology  (Taylor Available online 1994)
卷期: Volume 101, issue 1-6  

页码: 199-229

 

ISSN:0010-2202

 

年代: 1994

 

DOI:10.1080/00102209408951873

 

出版商: Taylor & Francis Group

 

关键词: Chlorinated hydrocarbons;incineration;moist CO oxidation;kinetic modeling

 

数据来源: Taylor

 

摘要:

The final destruction of toxic waste in incinerators occurs in the post flame region. The controlling chemistry in this region may be described as that of fuel-lean oxidation of CO in the presence of H2O and HCl perturbed by trace quantities of chlorinated hydrocarbons. In the present study, a reaction bath with initially about 1% of CO, O2, and H2O in nitrogen was perturbed by CH3Cl in a turbulent flow reactor operating at atmospheric pressure, with temperatures between 1000 and 1150 K. The equivalence ratio ranged from 0.25 to 1.0 and the initial CH3Cl ranged from 0 to 250ppm.

 

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