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Moderately Concentrated Polymer Solutions: Correlation of Flow Data by Simple Models

 

作者: F. Rodriguez,  

 

期刊: Transactions of the Society of Rheology  (AIP Available online 1966)
卷期: Volume 10, issue 1  

页码: 169-180

 

ISSN:0148-6055

 

年代: 1966

 

DOI:10.1122/1.549068

 

出版商: The Society of Rheology

 

数据来源: AIP

 

摘要:

A mathematical model was proposed recently which appears to correlate the flow curves for several polymers in aqueous solution over a wide range of shear rates and concentrations. New data for several nonaqueous systems as well as data from literature sources support the idea that the same equation can be applied to nonaqueous solutions. The equation relates relative viscosityηrat shear rateγ̇and shear stress τ to two parameters, the zero‐shear viscosityηroand the power input at the inflection pointBas follows:log ηr/log γro=0.68−0.32 erf[log(rγ̇/B)/2.272]whereerf(q)is the error function ofq. The parameterBappears to be a function of intrinsic viscosity but is not sensitive to polymer type or concentration. A comparison is made which indicates that the proposed model has advantages over other two‐parameter flow equations for real polymer systems where concentration is varied.

 

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