COMPLEXATION OF STRONTIUM IN THE SYNERGISTIC EXTRACTION SYSTEM DICYCLOHEXANO-18-CROWN-6, VERSATIC ACID, CARBON TETRACHLORIDE
作者:
BruceA. Moyer,
W. J. McDowell,
R. J. Ontko,
S. A. Bryan,
G. N. Case,
期刊:
Solvent Extraction and Ion Exchange
(Taylor Available online 1986)
卷期:
Volume 4,
issue 1
页码: 83-93
ISSN:0736-6299
年代: 1986
DOI:10.1080/07366298608917854
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The synergism in the extraction of Sr⊃ +⊃ from 0.5M Sr(NO⊂3⊂) ⊂2⊂ by 0.05M dicyclohexano-18-crown-6 (DC18C6) + 0.1M Versatic 1519 (abbreviated v-acid or RCOOH, a neo carboxylic acid) in CCl⊂4⊂ has been found to stem from a strong 1:1 interaction between DC18C6 and Sr⊃2+ ⊃ However, both nitrate and carboxylate can function as the anion for the (DC18C6)Sr⊃2+⊃ moiety. At aqueous conditions corresponding to less than complete loading (i.e., [Sr⊃2+⊃[ org < 0.05M for pH < 11.7), (DC18C6)Sr(NO⊂3;)⊂2⊂ precipitates as a solid. As the pH is raised in the interval 7 < pH < 11.7 to deprotonate the V-acid, the precipitate (DC18C6)Sr(NO⊂3⊂) ⊂2⊂ becomes solubilized first with probable formation of a mixed-anion complex and finally with quantitative (0.05M) formation of the monoraeric complex (DC18C6)Sr(OOCR) ⊂2⊂ H⊂2⊂O at pH = 11.7 as confirmed by viscometric titration of 0.05M DC18C6 in wet CCl⊂4⊂ with Sr(OOCR) ⊂2⊂, Karl-Fischer titrations, vapor-phase osmometry, and IR spectrophotometry.
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