Mechanism of the Radical Copolymerization of Methyl Methacrylate and Maleic Anhydride
作者:
Claude Caze,
Claude Loucheux,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1978)
卷期:
Volume 12,
issue 10
页码: 1501-1512
ISSN:0022-233X
年代: 1978
DOI:10.1080/00222337808069414
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The kinetics of the copolymerization of methyl methacrylate and maleic anhydride was investigated in benzenic solutions at 60 and 70° C and in bulk at 60°C. The microstructure of the copolymers was determined by1H-NMR and IR spectrophotometry. In benzene solutions the mechanism of copolymerization involves the participation of an associative species between both comonomers. In bulk a terminal model is sufficient to explain all the results.
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