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Synthesis and Characterization of New π-Conjugated Polymer Complexes with Transition Metal Fragments

 

作者: Hiroki Fukumoto,   Naoki Hayashida,   Tsukasa Maruyama,   Takakazu Yamamoto,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  （Taylor Available online 2000）
卷期: Volume 342, issue 1  

页码: 237-240

 

ISSN:1058-725X

 

年代: 2000

 

DOI:10.1080/10587250008038271

 

出版商: Taylor & Francis Group

 

关键词: π-conjugated polymer;π-conjugated polymer complex;ruthenium complex;poly(2,2′-bipyridine-5,5′-diyl);poly(2,2′-bipyrimidine-5,5′-diyl)

 

数据来源: Taylor

 

摘要:

Poly(2,2′-bipyridine-5,5′-diyl) (PBpy) (1) and a polymer of 2,2′-bipyrimidine (PBpym) (2) afford polymer complexes (3) and (4) coordinated with [Ru(bpy)2]2+fragments, respectively. The UV-vis spectrum of (4) in conc. H2SO4is considerably different from2in conc. H2SO4. The poly(6,6-dimethylbipyridine-5,5′-diyl) (P6MeBpy) (5) reacts with a ruthenium complex, [RuClCp*]4, (Cp*=pentamethylcyclopentadienyl) to give a new ruthenium complex (6).

 

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