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Crossed TM110bimodal cavity for measurement of dispersion electron paramagnetic resonance and saturation transfer electron paramagnetic resonance signals for biological materials

 

作者: C. Mailer,   H. Thomann,   B. H. Robinson,   L. R. Dalton,  

 

期刊: Review of Scientific Instruments  (AIP Available online 1980)
卷期: Volume 51, issue 12  

页码: 1714-1721

 

ISSN:0034-6748

 

年代: 1980

 

DOI:10.1063/1.1136162

 

出版商: AIP

 

数据来源: AIP

 

摘要:

When commercial reflection cavities are utilized for electron paramagnetic resonance (EPR) experiments at high‐microwave field intensities or for saturation transfer–electron paramagnetic resonance (ST–EPR) measurements, dispersion signals exhibit substantially worse signal‐to‐noise than absorption signals due to the increased sensitivity of the former to source frequency modulation noise. The development and testing of a TM110×TM110bimodal cavity which completely eliminates the source noise problem is described. This cavity is used to obtain EPR and ST–EPR spectra of a variety of commonly encountered spin‐labeled biological samples. When samples are contained in capillary tubes, this TM110×TM110cavity often permits the realization of better signal‐to‐noise than can be obtained with commercial reflection cavities.

 

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