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A description of chain slippage across the slip‐link in the dynamics of entangled linear polymers

 

作者: Kwang Man Kim,   Bong Ryuel Ryu,   In Jae Chung,  

 

期刊: Journal of Rheology  (AIP Available online 1994)
卷期: Volume 38, issue 3  

页码: 753-754

 

ISSN:0148-6055

 

年代: 1994

 

DOI:10.1122/1.550569

 

出版商: The Society of Rheology

 

关键词: LINEAR CHAINS;POLYMERS;STRESS RELAXATION;SLIP;DYNAMICS;POLYMER NETWORKS

 

数据来源: AIP

 

摘要:

A mechanism of chain slippage across the entanglement link is adopted to describe the early stage behavior in the stress relaxation of concentrated polymer systems. The chain slippage in the postulated mechanism occurs due to the equilibration of natural monomer (Rouse bead) densities between the primitive segmental units. It is shown that the processXintroduced by Lin can be confirmed theoretically and that it partially contributes to the reduction of stress discrepancy between the processesAandBof Doi.

 

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