A description of chain slippage across the slip‐link in the dynamics of entangled linear polymers
作者:
Kwang Man Kim,
Bong Ryuel Ryu,
In Jae Chung,
期刊:
Journal of Rheology
(AIP Available online 1994)
卷期:
Volume 38,
issue 3
页码: 753-754
ISSN:0148-6055
年代: 1994
DOI:10.1122/1.550569
出版商: The Society of Rheology
关键词: LINEAR CHAINS;POLYMERS;STRESS RELAXATION;SLIP;DYNAMICS;POLYMER NETWORKS
数据来源: AIP
摘要:
A mechanism of chain slippage across the entanglement link is adopted to describe the early stage behavior in the stress relaxation of concentrated polymer systems. The chain slippage in the postulated mechanism occurs due to the equilibration of natural monomer (Rouse bead) densities between the primitive segmental units. It is shown that the processXintroduced by Lin can be confirmed theoretically and that it partially contributes to the reduction of stress discrepancy between the processesAandBof Doi.
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