The Effects of Plasma Irradiation on Saccharides
作者:
D.M. Soignet,
O. Hinojosa,
T.L. Ward,
R.R. Benerito,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1982)
卷期:
Volume 17,
issue 3
页码: 403-414
ISSN:0022-233X
年代: 1982
DOI:10.1080/00222338208056480
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Monosaccharides and polysaccharides are chemically modified when they are subjected to rf plasmas derived from oxygen, nitrogen, or argon. The plasma treatment converts hydroxyl groups within the bulk to carbonyl groups on the order of one per anhydroglucose unit. On the surface, the concentration of carbonyl groups is greater than in the bulk. The activated surfaces formed by the plasma treatments are stable for at least 1.5 h. The observed spectral (IR, ESCA, and ESR) changes of the irradiated samples are the direct result of the plasma and not the secondary result of plasma-activated surfaces reacting with the atmosphere.
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