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Structure of Nickel Chromite

 

作者: E. Prince,  

 

期刊: Journal of Applied Physics  (AIP Available online 1961)
卷期: Volume 32, issue 3  

页码: 68-69

 

ISSN:0021-8979

 

年代: 1961

 

DOI:10.1063/1.2000504

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Nickel chromite is a normal spinel whose structure has atetragonal distortion below about 310°K. The structure parametershave been determined by neutron diffraction at 77°K, at whichtemperature thec/aratio of a face-centered unit cell is 1.04. Thespace group isI41/amdwith four Ni ions in positions 4(a), eightCr ions in positions 8(d), and 16 O ions in positions 16(h) withy = 0.239andz = 0.392. The two independent Cr-O distances are1.98 A and 1.99 A, indicating that the octahedron is not greatlydistorted. The tetrahedron around the nickel is elongated bynearly 14% parallel to thecaxis. Below a Curie temperature ofabout 65°K, nickel chromite has a small ferromagnetic moment.The neutron diffraction pattern at 4.2°K shows extra peaks whichcan be indexed on the basis of a primitive cell having the samedimensions as the body-centered chemical cell. The intensities ofthese peaks cannot be accounted for by any simple model for themagnetic structure. In fact, a systematic search of possiblestructures belonging to magnetic space groups with symmetriesas low as classesm′m′2 andmm′2′ has failed to turn up anystructure which is consistent with the diffraction data.

 

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