Utility of 5-Diazo-1,2,4- Triazol-3-Carboxylic Acid for Colorimetric Determination of Certain 8-Hydroxyquinolines
作者:
NawalA. El-Koussi,
Abd El-Maaboud,
I. Mohamed,
HorriaA. Mohamed,
ZeinabS. Fargaly,
期刊:
Analytical Letters
(Taylor Available online 1996)
卷期:
Volume 29,
issue 14
页码: 2487-2498
ISSN:0003-2719
年代: 1996
DOI:10.1080/00032719608002786
出版商: Taylor & Francis Group
关键词: 8-hydroxyquinolines;diazotriazole carboxylic acid;colorimetry
数据来源: Taylor
摘要:
A colorimetric method for the determination of certain 8-hydroxyquinolines has been developed. The method is based on the coupling of 8-quinolinols with diazotriazole carboxylic acid in the presence of sodium carbonate (0.5% w/v) at ambient temperature (around 30°C). The resulting azo dyes are stable and give intense absorption in the range of 486–540 nm. Beer's law is valid in the concentration ranges of 1 – 8, 2.5 – 17.5, 5 – 35, 2 – 20, and 2 – 20 mcg/ml for 8-hydroxyquinoline (HQ), 5,7-diiodo-8-hydroxyquinoline (DIQ), 5,7-dibromo-8-hydroxyquinoline (DBQ), 5-chloro-7-iodo-8-hydroxyquinoline (CIQ) and 8-hydroxy-7-iodo-5-quinoline sulfonic acid (SIQ), respectively. The proposed method has been successfully applied for the determination of the studied compounds in pure form and in commercial formulations. The obtained results are in good agreement with those obtained from reported methods.
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