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A Pressure Counterbalancing Apparatus for the Measurement of the Electrical Conductivity of Aqueous Solutions above Their Critical Temperatures

 

作者: J. K. Fogo,   C. S. Copeland,   S. W. Benson,  

 

期刊: Review of Scientific Instruments  (AIP Available online 1951)
卷期: Volume 22, issue 10  

页码: 765-769

 

ISSN:0034-6748

 

年代: 1951

 

DOI:10.1063/1.1745758

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The apparatus described is used in the measurement of the electrical conductivity of vapor phase systems at temperatures to 400°C and pressures to 4500 psi. A small, lightly constructed, platinum‐iridium conductivity cell is enclosed in a larger, heated, steel pressure vessel. The pressure developed in the conductivity cell on heating is counterbalanced by admitting nitrogen into the pressure vessel. The direction and magnitude of the pressure differential between the vapor in the cell and the surrounding nitrogen is indicated by a meter circuit which measures the potential drop of a radiofrequency current across a variable condenser which is operated by an aneroid diaphragm on the cell. Admission and release of nitrogen is controlled manually. Measurements of the cell resistance are made by conventional ac bridge methods and are not described.

 

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