Kinetic Studies of Ethyl N-Hydroxymethyl Carbamate
作者:
D.M. Soiget,
R.J. Berni,
J.I. Wadsworth,
R.R. Benerito,
期刊:
Analytical Letters
(Taylor Available online 1972)
卷期:
Volume 5,
issue 6
页码: 395-406
ISSN:0003-2719
年代: 1972
DOI:10.1080/00032717208066115
出版商: Taylor & Francis Group
关键词: ethy1 N-hydroxymethycarbamate;formaldehyde;polarography;computer program;kinetics;ethyl N-methylolcarbamate
数据来源: Taylor
摘要:
Kinetics of the dissociation of ethy1 N-hydroxymethylcarbamate, and monomethylolethylcarbamate (MMEC) at various temperatures and pH values have been studied by measuring the formaldehyde concentration in solution via an electrochemical technique. Formaldehyde and ethyl carbamate (EC) are the products of the dissociation. Formaldehyde concentration as a function of time has been used in a computer program designed to calculate the rate constant, kf, for the formation of MMEC form formaldehyde and EC and the rate constant, kr, for the dissociation of MMEC.
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