Synthesis of Inorganic-Organic Oligomers Including Cyclotriphosphazenes and the Adhesive Properties of the Products
作者:
M. Kajiwara,
H. Saito,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1981)
卷期:
Volume 16,
issue 4
页码: 873-879
ISSN:0022-233X
年代: 1981
DOI:10.1080/00222338108056832
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The reaction of diaminotetraalkoxy- and aryloxycyclotriphos-phazene with toluendiisocyanate (TDI) was investigated in various solvents. It was found that benzene or electron negative groups such as the trifluoroethoxy group (-OCH2CF3) were the most suitable solvents for the growing of molecules having an N3P3ring. The adhesive property of the products to a hard polyvinyl chloride laminate was studied by bonding strength measurements. The product formed from the reaction of diaminotetramethoxy-cyclotriphosphazene with TDI had the strongest adhesive strength even though it had the low molecular weight.
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