The physical characteristics, thermoelectric power, resistivity, specific heat conductivity, and the temperature difference between hot and cold junctions determine the efficiency of thermocouple materials. These data have been determined for ChromelP‐constantan, bismuth alloys, and the intermetallic compound ZnSb, containing small amounts of added metals.The optimum characteristics of flat‐plate type solar energy collectors have been evaluated in combination with thermocouples, designed for maximum energy conversion. Using flat‐plate collectors with 2 glass panes, an efficiency of 0.63 percent was obtained with the ZnSb‐type alloys in combination with a negative Bi‐alloy. The commercially available ductile alloys ChromelP‐constantan, produced ten times lower efficiency. Calculations indicate that the efficiency may be increased to 1.05 percent by using 4 panes of low‐reflection characteristics.With solar energy concentrating means (lenses), the efficiency was increased to 3.35 percent, using the above mentioned best alloy combination.The maximum allowable cost of thermoelectric generators has been evaluated, by comparison with present methods of electric power generation.Solar thermoelectric generators may find useful application in the tropics, as they do not contain moving parts and require very little attention. Further development is needed to determine their economical value.