首页   按字顺浏览 期刊浏览 卷期浏览 Aging Effects on the Rheology of LC Solutions of Hydroxypropylcellulose
Aging Effects on the Rheology of LC Solutions of Hydroxypropylcellulose

 

作者: C.R. Leal,   M.H. Godinho,   A.F. Martins,   F. Fried,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  (Taylor Available online 1995)
卷期: Volume 261, issue 1  

页码: 87-93

 

ISSN:1058-725X

 

年代: 1995

 

DOI:10.1080/10587259508033455

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

We apply the recently developed continuum theory of liquid crystalline polymers1to interpret the behavior of the shear viscosity η(γ.) and the first normal-stress difference N1(γ.) measured for liquid crystalline solutions (c = 37%, c > c*) of HPC (Aldrich, Mw= 100,000) in acetic acid (AA) with different ages: 1 day, 1 month and 2 years. η(γ.) and N1(γ.) were measured over four decades in γ. N1(γ.) is observed to change from positive to negative and again to positive, as the shear rate γ. increases. η(γ.) shows a small newtonian plateau at low shear rates and a strong shear-thinning at higher values of γ. The rate of decrease of η(γ.) in this region is not monotonous, as usual, but shows an “hesitation” similar to one previously observed in a different system2. The aging effect promotes a “depolymerization”3of HPC. This, in turn, should have a strong influence on the behavior of Nl(γ.) and η(γ.) which is indeed observed4. All these observations can be rationalized within the framework of the theory1.

 

点击下载:  PDF (287KB)



返 回