Selective ion electrode measurements of chloride concentrations in the determination of cation exchange capacities of soils
作者:
R.St.C. Smart,
A.D. Thomas,
D.P. Drover,
期刊:
Communications in Soil Science and Plant Analysis
(Taylor Available online 1974)
卷期:
Volume 5,
issue 1
页码: 1-11
ISSN:0010-3624
年代: 1974
DOI:10.1080/00103627409366475
出版商: Taylor & Francis Group
关键词: Cation exchange capacity;chloride selective ion electrode;ammonium ion interference
数据来源: Taylor
摘要:
The determination of chloride ion in soil extracts for cation exchange capacity in the presence of ammonium ions of nearly equal concentration (∼5 x 10‐2M) and excess sodium sulphate (0.5 M) by an Orion solid state selective ion electrode is reported. Ammonium ions were found to interfere by reducing the determined value of the chloride ion by up to 20%. This interference effect was compensated by the determination of a mean activity coefficient for ammonium chloride in the sodium sulphate medium. This method was accurate to ±7%. No interference effect was found for the chloride ion determination of a mixed sodium chloride‐sodium sulphate solution.
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