Addition of arylfluorosilanes containing silicon-attached hydrogen
作者:
E.A.Chernyshev,
M.E.Dolgaya,
E.D.Lubuzh,
期刊:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science
(Springer Available online 2004)
卷期:
Volume 14,
issue 4
页码: 629-632
ISSN:0568-5230
年代: 2004
DOI:10.1007/BF00846717
出版商: Springer_US-Boston
数据来源: Springer
摘要:
1.In additions to unsaturated compounds in presence of a H2PtCl6catalyst, hydride arylfluorosilanes are considerably more reactive than their chloro analogs.2.The arylfluorosilyl groups of difluorophenylsilane and difluoro-1-naphthylsilane add at both of the carbon atoms of the vinyl group of styrene (mainly at the α-carbon atom), whereas the dichlorophenylsilyl group of dichlorophenylsilane adds only, to the end carbon atom of the double bond. The fluorodiphenylsilyl group of fluorodiphenylsilane adds to almost equal extents at both carbon atoms of the vinyl group of styrene.3.In high-temperature condensation with chlorobenzene the replacement of the chlorine atoms of dichlorophenylsilane by fluorine atoms leads to a reduction in the ratio of condensation and reduction products
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