GAS HYDRATE FORMATION IN COLLOIDAL MATRICES
作者:
Harald Fördedal,
Øystein Holt,
Johan Sjöblom*,
期刊:
Journal of Dispersion Science and Technology
(Taylor Available online 1994)
卷期:
Volume 15,
issue 4
页码: 465-486
ISSN:0193-2691
年代: 1994
DOI:10.1080/01932699408943570
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The hydrocarbon rich phase (L2) of the system trichlorofluoromethane CCl3F / water (electrolyte) / nonionic surfactant has been investigated by means of NMR self-diffusion measurements, and dielectric spectroscopy. The dielectric spectra were recorded between 50 MHz and 5 GHz and fitted to a Cole-Cole model function with an additional Debye term. The main relaxation was due to a polarization inside the aqueous droplets (Maxwell-Wagner-Sillars relaxation). The NMR self-diffusion data display a low molecular self-diffusion for both water and surfactant over a broad interval consistent with a droplet structure. However at the highest CCl3F concentrations the rapid diffusion of the nonionic surfactant reveals that the aqueous droplets are most likely stabilized by means of gas hydrates at the w/o microemulsion interface.
点击下载:
PDF (485KB)
返 回