Analysis of the Molecular Weight Distributions of Aminolyzed Poly(Ethylene Terephthalate) by Using Gel Permeation Chromatography
作者:
MarthaJ. Collins,
S.Haig Zeronian,
MaritaL. Marshall,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1991)
卷期:
Volume 28,
issue 8
页码: 775-792
ISSN:0022-233X
年代: 1991
DOI:10.1080/00222339108054056
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The molecular weight distributions of poly(ethylene terephthalate) fibers aminolyzed with selected primary amines (namely, methylamine, ethylamine,n-butylamine, and ethanolamine) were determined by using gel permeation chromatography. Initially the shape of the differential molecular weight distribution (DMWD) curve did not change although its peak shifted to lower molecular weights. As aminolysis continued, a shoulder appeared on the DMWD curve. Its appearance seemed to coincide with an increase in the density of the product. Ultimately, distinct molecular populations could be identified in the treated polymer depending on the severity of the aminolysis and the selectivity of the particular amine. The lowest is thought to represent primarily crystalline residues and has a peak molecular weight of 3400. The relations betweenMnand ultimate tenacity and breaking strain for the aminolyzed products were linear.
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