Polydispersity Effect on the Spectrum of Light Scattered by Polymers with Nearest- and Next-nearest-neighbour Interactions
作者:
I.A. Hadjiagapiou,
期刊:
Optica Acta: International Journal of Optics
(Taylor Available online 1982)
卷期:
Volume 29,
issue 11
页码: 1543-1555
ISSN:0030-3909
年代: 1982
DOI:10.1080/713820784
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The effect of polydispersity on the total integrated intensity and spectral density of light scattered by linear polymers in dilute solution is studied. Use is made of the chain model with nearest- and next-nearest-neighbour linear interactions. The length distribution is chosen to be that of Schulz. The analysis proceeds via normal mode decomposition, and the centre of mass contribution to the spectral density—as well as that of the normal modes, with and without mixing—becomes visible. The influence of polydispersity and elastic constants is significantly manifested in the normal mode contributions, and the spectral density curves of the polydisperse system are narrower than those of the monodisperse case.
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