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Computational Chemical Analysis of the Separation of Derivatized R- and S-Amino Acid Enantiomers on N-(tert-Butylaminocarbonyl)-(S)-valylamino- propylsilica Gel and (R)-1-(α-Naphthyl)-ethylaminocarbonyl-glycylamino-propylsilica Gel by Liquid Chromatography

 

作者: Toshihiko Hanai,   Hiroyuki Hatano,   Noriyuki Nimura,   Toshio Kinoshita,  

 

期刊: Journal of Liquid Chromatography & Related Technologies  （Taylor Available online 1996）
卷期: Volume 19, issue 8  

页码: 1189-1204

 

ISSN:1082-6076

 

年代: 1996

 

DOI:10.1080/10826079608006312

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The chiral selectivities of N-(tert.-butylaminocarbonyl)-(S)-valylaminopropylsilica gel and (R)-1-(α-naphthyl)-ethyl-aminocarbonyl-glycylaminopropylsilica gel were studied using model compounds. The differences in the final energy values of molecular interactions between the model chiral phase and derivatized (R)-and (S)-amino acids, calculated by molecular.

 

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