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Preparation of Novel Lipophilic GABA analogues containing cyclopropane rings via cyclopropanation ofN‐silylated unsaturated amines

 

作者: Klaus Paulini,   Hans‐Ulrich Reißig,  

 

期刊: Journal für Praktische Chemie/Chemiker‐Zeitung  （WILEY Available online 1995）
卷期: Volume 337, issue 1  

页码: 55-59

 

ISSN:0941-1216

 

年代: 1995

 

DOI:10.1002/prac.19953370112

 

出版商: WILEY‐VCH Verlag GmbH

 

数据来源: WILEY

 

摘要:

AbstractNovel lipophilic γ‐amino acids8and9analogous to GABA containing cyclopropane rings are synthesized by Rh(II)‐catalyzed reaction of diazo compounds2and3withN,N‐bis(trimethylsilyl)allylamine(1)and subsequent hydrolysis. In addition, routes are described leading to the vinylogous GABA analogue15and to the unusual tricyclic γ‐ami

 

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