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Structure of Partly Quenched Molten Copper Chloride

 

作者: G. Pastore,   H. Tatlipinar,   M.P. Tosi,  

 

期刊: Physics and Chemistry of Liquids  (Taylor Available online 1996)
卷期: Volume 31, issue 2  

页码: 89-96

 

ISSN:0031-9104

 

年代: 1996

 

DOI:10.1080/00319109608029562

 

出版商: Taylor & Francis Group

 

关键词: Ionic mobility;superionic glass

 

数据来源: Taylor

 

摘要:

The structural modifications induced in a model of molten CuCl by quenching the chlorine component into a microporous disordered matrix are evaluated using the hypernetted-chain closure in Ornstein-Zernike relations for the pair distribution functions in random systems. Aside from obvious changes in the behaviour of long-wavelength density fluctuations, the main effect of partial quenching is an enhanced delocalization of the Cu+ions. The model suggests that the ionic mobility in a superionic glass is enhanced relative to the melt at the same temperature and density. Only very minor quantitative differences are found in the structural functions when the replica Onstein-Zernike relations derived by Given and Stell for a partly quenched system are simplified to those given earlier by Madden and Glandt.

 

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