Structure of Partly Quenched Molten Copper Chloride
作者:
G. Pastore,
H. Tatlipinar,
M.P. Tosi,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1996)
卷期:
Volume 31,
issue 2
页码: 89-96
ISSN:0031-9104
年代: 1996
DOI:10.1080/00319109608029562
出版商: Taylor & Francis Group
关键词: Ionic mobility;superionic glass
数据来源: Taylor
摘要:
The structural modifications induced in a model of molten CuCl by quenching the chlorine component into a microporous disordered matrix are evaluated using the hypernetted-chain closure in Ornstein-Zernike relations for the pair distribution functions in random systems. Aside from obvious changes in the behaviour of long-wavelength density fluctuations, the main effect of partial quenching is an enhanced delocalization of the Cu+ions. The model suggests that the ionic mobility in a superionic glass is enhanced relative to the melt at the same temperature and density. Only very minor quantitative differences are found in the structural functions when the replica Onstein-Zernike relations derived by Given and Stell for a partly quenched system are simplified to those given earlier by Madden and Glandt.
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