Electron Transfer Reactions Between Iron (III) and Substituted Ferrocenes in Cationic and Non‐Ionic Micellar Systems
作者:
Antonio I. Carbone,
F. Paolo Cavasino,
Carmelo Sbriziolo,
Ezio Pelizzetti,
期刊:
Berichte der Bunsengesellschaft für physikalische Chemie
(WILEY Available online 1985)
卷期:
Volume 89,
issue 1
页码: 31-35
ISSN:0005-9021
年代: 1985
DOI:10.1002/bbpc.19850890108
出版商: Wiley‐VCH Verlag GmbH&Co. KGaA, Weinheim
关键词: Chemical Kinetics;Electron Transfer Reaction;Micelles;Surfactants
数据来源: WILEY
摘要:
AbstractThe kinetics of the electron transfer reactions of aquoiron(III) with ferrocene (Fer) and its n‐butyl (BFer), 1,1′‐dimethyl (DMFer) and 1,1′‐di‐n‐butyl (DBFer) derivatives have been studied in the presence of cationic (CTAN) and non‐ionic (Triton X‐100) micelles at 20.0°C and ionic strength 0.02 mol dm−3. Both surfactants inhibit nearly at the same extent the reaction involving a given ferrocene derivative. The rate inhibition depends strongly on the alkyl groups present in the molecule of ferrocene, following the order DBFer>BFer>DMFer>Fer. The binding constants and the contribution of a methylene (or methyl) group of the alkyl substituents to the transfer free energy from water to micelle have been estimated and discussed, suggesting that ferrocenes are locate
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