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Conversion of oleic acid to 17‐ and 18‐substituted stearic acid derivatives by way of the „acetylene zipper”︁

 

作者: Kim E. Augustin,   Hans J. Schäfer,  

 

期刊: Liebigs Annalen der Chemie  （WILEY Available online 1991）
卷期: Volume 1991, issue 10  

页码: 1037-1040

 

ISSN:0170-2041

 

年代: 1991

 

DOI:10.1002/jlac.1991199101178

 

出版商: WILEY‐VCH Verlag

 

关键词: Fatty acid;Oleic acid;Stearic acid, 17‐ and 18‐substituted;Acetylene zipper

 

数据来源: WILEY

 

摘要:

AbstractStearolic acid (2) was prepared from oleic acid (1) and converted to4, 5, and7by way of the „acetylene zipper”︁ reaction. Compounds5and7were transformed to the (ω – 1) ketones8and9and dimerized by way of the Glaser coupling reaction to11and12. At daylight,12polymerizes to a blue

 

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