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Effect of the Adsorption of Monovalent Intermediate on the Kinetics of Two‐Step Charge Transfer of Metal/Metal Ion Electrode

 

作者: I. H. Plonski,  

 

期刊: Berichte der Bunsengesellschaft für physikalische Chemie  （WILEY Available online 1991）
卷期: Volume 95, issue 1  

页码: 23-31

 

ISSN:0005-9021

 

年代: 1991

 

DOI:10.1002/bbpc.19910950105

 

出版商: Wiley‐VCH Verlag GmbH&Co. KGaA

 

关键词: Adsorption;Electrochemistry

 

数据来源: WILEY

 

摘要:

AbstractTheoretical relationships for the kinetics of two‐step charge transfer of bivalent metal were derived taking into account the adsorption of the intermediate according to the Langmuir isotherm. The polarization transients can exhibit inductive behaviour in two anodic and two cathodic particular cases. Inductive transients in the range of low Tafel slope are exclude

 

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