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The Structure and Chemical Bond Peculiarities of Si, Ti, Zr and Hf Complex Fluoride Hydrates

 

作者: M.L. Afanasjev,   S.P. Gabuda,   R.L. Davidovich,   A.A. Matsutsyn,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1969）
卷期: Volume 2, issue 1  

页码: 19-24

 

ISSN:0038-7010

 

年代: 1969

 

DOI:10.1080/00387016908050008

 

出版商: Taylor & Francis Group

 

关键词: metal fluorocomplexes;NMR spectra

 

数据来源: Taylor

 

摘要:

Compounds with the common formula MAF6.6H2O, where M is a bivalent transition metal and A a quadrivalent element, form a large series of fluorocomplexes which so far has undergone little study. Besides MAF6.6H2O, zirconium and hafnium likewise form more complex compounds with the composition1M2AF8.12H2O and Cd2AF8.6H2O, their complex anion structure still being vague.

 

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