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Paracrystalline Structure of Polymer‐Crystal Lattice Distortion Induced by Electron Irradiation

 

作者: Toshio Nagasawa,   Keinosuke Kobayashi,  

 

期刊: Journal of Applied Physics  (AIP Available online 1970)
卷期: Volume 41, issue 11  

页码: 4276-4284

 

ISSN:0021-8979

 

年代: 1970

 

DOI:10.1063/1.1658457

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The melting temperature of polyethylene crystals decreases and the lattice constants (bothaandb) and lattice distortion increase, but the macroscopic volume of the specimen does not change with electron irradiation. From these results a model of a deformed lattice structure with point defects produced by irradiation is proposed. Calculations indicate that the anisotropy of a polymer crystal (difference between the elastic modulus along the molecular axis and perpendicular to the axis) increases the range of the distortion in a crystal caused by a defect. The presence of lattice distortion in electron irradiated polymer single crystals produces observable features in the Moire´ patterns obtained from the crystals.

 

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