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Electrochemical Oxidation of Derivatives of Dibenzodiazepin. Dibenzothiazepin and Dibenzoxazepin

 

作者: J.-M. Kauffmann,   G.J. Patriarche,   G.D. Christian,  

 

期刊: Analytical Letters  （Taylor Available online 1979）
卷期: Volume 12, issue 11  

页码: 1217-1234

 

ISSN:0003-2719

 

年代: 1979

 

DOI:10.1080/00032717908067911

 

出版商: Taylor & Francis Group

 

关键词: Electrochemistry;cyclic voltammetry;nonaqueous solvents;clozapin;clothiapin;loxapin

 

数据来源: Taylor

 

摘要:

Clozapin exhibits two anodic waves at ≥ 1 M H2SO4, but at lower acidities only the first two-electron wave remains. Cyclic voltammetry shows an ECE mechanism. Reversibility decreases at ≥ 10−4Mconcentrations, due to formation of an adsorptiob film. In nonaqueous solvents two irreversible one-electron waves appear. Clothiapin and loxapin are more difficultly oxidized and can be measured in the presence of clozapin.

 

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