The homogeneous gas phase H2D2metathesis at room temperature: Reaction induced by specific vibrational excitation
作者:
S. H. Bauer,
D. M. Lederman,
E. L. Resler,
E. R. Fisher,
期刊:
International Journal of Chemical Kinetics
(WILEY Available online 1973)
卷期:
Volume 5,
issue 1
页码: 93-106
ISSN:0538-8066
年代: 1973
DOI:10.1002/kin.550050109
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractWe have demonstrated that reactions for which substantial activation energies are needed can be induced to occur at room temperature via specific vibrational excitation. Indeed, the indications are that the atom‐switching reactions for whichEa>25 kcal take place with high probability only when the activation energy is localized in the vibrational mode. In this preliminary report on the utilization of the stimulated Raman effect to generate substantial populations in the critical vibrational states required for the homogeneous atom exchange between H2and D2, we first summarized the historical development of the concept. The experimental arrangement is then described and the analytical results tabulated; the observed dependence on relative concentrations is semiquantitatively rationalized on the basis of a model proposed in 1964. Independent shock tube and molecular beam investigations were similarly accounted for. Attention is called to the discrepancy between the generally concordant experimental results and theab initioquantum mechanical calculations of the potential energy surface for 4H atom
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