Infrared Spectrum of the Cyclopentylmethyl Free Radical
作者:
J. Pacansky,
R.J. Waltman,
期刊:
Spectroscopy Letters
(Taylor Available online 1989)
卷期:
Volume 22,
issue 6
页码: 739-745
ISSN:0038-7010
年代: 1989
DOI:10.1080/00387018908053932
出版商: Taylor & Francis Group
关键词: Infrared Spectrum;Cyclopentylmethyl;Radical;Matrix Isolation
数据来源: Taylor
摘要:
The cyclopentylmethyl free radical has been generated in argon matrices by UV irradiation of the corresponding diacyl peroxide at T = 20K. The infrared spectrum of the radical reveals an out-of-plane deformation of the radical center at 563 cm−1characteristic of primary alkyl radicals.
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