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Infrared Spectrum of the Cyclopentylmethyl Free Radical

 

作者: J. Pacansky,   R.J. Waltman,  

 

期刊: Spectroscopy Letters  (Taylor Available online 1989)
卷期: Volume 22, issue 6  

页码: 739-745

 

ISSN:0038-7010

 

年代: 1989

 

DOI:10.1080/00387018908053932

 

出版商: Taylor & Francis Group

 

关键词: Infrared Spectrum;Cyclopentylmethyl;Radical;Matrix Isolation

 

数据来源: Taylor

 

摘要:

The cyclopentylmethyl free radical has been generated in argon matrices by UV irradiation of the corresponding diacyl peroxide at T = 20K. The infrared spectrum of the radical reveals an out-of-plane deformation of the radical center at 563 cm−1characteristic of primary alkyl radicals.

 

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