Kinetics of Intercalation of Br2or ICI into Pyrolytic Graphite “NIKAFILM” Studied by Thermoelectric Properties
作者:
Ikushi Yoshida,
Seiichi Tanuma,
Takafumi Ono,
Naoki Sato,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 2000)
卷期:
Volume 340,
issue 1
页码: 31-36
ISSN:1058-725X
年代: 2000
DOI:10.1080/10587250008025438
出版商: Taylor & Francis Group
关键词: intercalation;graphite;bromine;iodine monochloride;Seebeck coefficient
数据来源: Taylor
摘要:
The kinetics of intercalation of halogen molecules Br2or ICI into pyrolytic graphite “NIKAFILM”, a commercial product of Nihon Carbon Inc., has been studied by the measurement of electron transport phenomena, especially the thermoelectric properties. The data were analyzed by a two-carriers band model, and it was concluded that the change in the resistivity and Seebeck coefficient is due to the increase in the positive hole density because the intercalant halogen molecules work as acceptors. From the weight increment the stage index was tentatively estimated to be four, and the deduced charge transfer rate was 1.33 × 10−4e/mole-cule.
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