Kinetics and mechanism of the iodine oxidation of hydroxylamine
作者:
Robert T. Wang,
Gyula Rábai,
Kenneth Kustin,
期刊:
International Journal of Chemical Kinetics
(WILEY Available online 1992)
卷期:
Volume 24,
issue 1
页码: 11-18
ISSN:0538-8066
年代: 1992
DOI:10.1002/kin.550240103
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractStudies of the stoichiometry and kinetics of the reaction between hydroxylamine and iodine, previously studied in media below pH 3, have been extended to pH 5.5. The stoichiometry over the pH range 3.4–5.5 is 2NH2OH + 2I2= N2O + 4I−+ H2O + 4H+. Since the reaction is first‐order in [I2] + [I3−], the specific rate law,k0, isk0= (k1+k2/[H+]) {[NH3OH+]0/(1 + Kp[H+])} {1/(1 + KI[I−])}, where [NH3OH+]0is total initial hydroxylamine concentration, andk1,k2, Kp, and KIare (6.5 ± 0.6) × 105M−1s−1, (5.0 ± 0.5) s−1, 1 × 106M−1, and 725 M−1, respectively. A mechanism taking into account unprotonated hydroxylamine (NH2OH) and molecular iodine (I2) as reactive species, with intermediates NH2OI2−, HNO, N
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