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Inter and Intramolecular Contributions to the Proton Dipolar and Rotating Frame Spin-Lattice Relaxation Times in the Nematic Phase of the Liquid Crystal 5CB-d11

 

作者: J.S. Lewis,   E. Tomchuk,   E. Bock,  

 

期刊: Molecular Crystals and Liquid Crystals  (Taylor Available online 1983)
卷期: Volume 97, issue 1  

页码: 387-396

 

ISSN:0026-8941

 

年代: 1983

 

DOI:10.1080/00268948308073165

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

An isotopic dilution study of the proton dipolar and rotating frame spin-lattice relaxation times (T1DandT1p) in the nematic liquid crystal 4-cyano-4′-n-pentyl-d11-biphenyl (5CB-d11) at 13.8 MHz over the nematic phase temperature range was used to separate the intermolecular and intramolecular contributions to the ring proton relaxation rates. This is the first such study to be reported. Combined with our earlier proton study of inter/intra Zeeman spin-lattice relaxation (T1) in 5CB-d11, these data permit a critical study of the soft-mode dynamics in the system. A qualitative explanation of theT1D> results is presented, but a complete explanation of theT1presults is not possible with existing theory.

 

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