首页   按字顺浏览 期刊浏览 卷期浏览 Chiral Induction in Originally Racemic Amino Acidsvia5‐Acyl and 5‐Acyloxyaminooxazoles
Chiral Induction in Originally Racemic Amino Acidsvia5‐Acyl and 5‐Acyloxyaminooxazoles

 

作者: Bruce H. Lipshutz,   Randall W. Hungate,   Keith E. Mccarthy,  

 

期刊: Israel Journal of Chemistry  （WILEY Available online 1986）
卷期: Volume 27, issue 1  

页码: 49-55

 

ISSN:0021-2148

 

年代: 1986

 

DOI:10.1002/ijch.198600009

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

AbstractA variety of chiral 2,4‐disubstituted‐5‐trifluoroacetamido‐,5‐carbobenzyloxyamino, and 5‐β,β,β,‐trichloroethoxycarbonylaminooxazoles have been prepared from diamide, dipeptide, or amide nitrile precursors. Conversion to their (poly)amide equivalentsviaa deacylation/hydration sequence is described. The extent of induction of chirality realized upon ring opening in each case is de

 

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