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The synthesis of indazolesvia2,3‐dihydroindazoles

 

作者: Gladys S. Zenchoff,   Armin Walser,   R. Ian Fryer,  

 

期刊: Journal of Heterocyclic Chemistry  (WILEY Available online 1976)
卷期: Volume 13, issue 1  

页码: 33-39

 

ISSN:0022-152X

 

年代: 1976

 

DOI:10.1002/jhet.5570130105

 

出版商: Wiley‐Blackwell

 

数据来源: WILEY

 

摘要:

AbstractThe preparation and oxidation of 2,3‐dihydroindazoles to 1H, 2Hor 3H‐indazoles is described. A method for the synthesis of indazole 2‐oxides has been found. Oxidation of 2‐acetyl‐2,3‐dihydro‐3,3‐disubstituted indazoles5aand5cgave quinoid compounds20a, 20b, 24aand24b, which could be isomerized to 3H‐indazoles upon removal of the acetyl group. A quinoid compound21was also obtained on treatment of5awith t

 

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