The synthesis of indazolesvia2,3‐dihydroindazoles
作者:
Gladys S. Zenchoff,
Armin Walser,
R. Ian Fryer,
期刊:
Journal of Heterocyclic Chemistry
(WILEY Available online 1976)
卷期:
Volume 13,
issue 1
页码: 33-39
ISSN:0022-152X
年代: 1976
DOI:10.1002/jhet.5570130105
出版商: Wiley‐Blackwell
数据来源: WILEY
摘要:
AbstractThe preparation and oxidation of 2,3‐dihydroindazoles to 1H, 2Hor 3H‐indazoles is described. A method for the synthesis of indazole 2‐oxides has been found. Oxidation of 2‐acetyl‐2,3‐dihydro‐3,3‐disubstituted indazoles5aand5cgave quinoid compounds20a, 20b, 24aand24b, which could be isomerized to 3H‐indazoles upon removal of the acetyl group. A quinoid compound21was also obtained on treatment of5awith t
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