Departures from random mixing in polymer‐liquid systems
作者:
C. Booth,
G. Gee,
G. R. Williamson,
期刊:
Journal of Polymer Science
(WILEY Available online 1957)
卷期:
Volume 23,
issue 103
页码: 3-8
ISSN:0022-3832
年代: 1957
DOI:10.1002/pol.1957.1202310302
出版商: Interscience Publishers, Inc.
数据来源: WILEY
摘要:
AbstractThe vaper pressure of ethyl acetate‐natural rubber mixtures has been studied at 25 and 50°C. over the whole range of miscibility. Current statistical theories of polymer solutions fail to account quantitatively for the observed entropy of mixing; the discrepancy is attributed to the occurrence in this system of non‐random mi
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