Comparison of Fluorimetric Reagents for the Analysis of Aluminum in Mineral Waters
作者:
C. Sabbioni,
M.A. Raggi,
G. Casamenti,
G. Varani,
Q. Zini,
期刊:
Analytical Letters
(Taylor Available online 1999)
卷期:
Volume 32,
issue 1
页码: 123-137
ISSN:0003-2719
年代: 1999
DOI:10.1080/00032719908542603
出版商: Taylor & Francis Group
关键词: Aluminum;Mordant Red 19 reagent;Molecular Spectrofluorimetric Method;Mineral Water
数据来源: Taylor
摘要:
The paper describes a simple and sensitive spectrofluorimetric procedure for the analysis of microquantities of aluminum in drinking water for toxicological purposes. The method is based on the formation of the Al(III) – Mordant Red 19 complex, after a comparative study of the complexes formed with several compounds of the Mordant family. The emission of the fluorescent complex was measured at λ = 555 nm with excitation at λ = 475 nm. A good linearity was found in the 1 – 80 ng ml−1of aluminum range. The precision of the method was good, the intraday Relative Standard Deviation being 1.9% for a 30 ng ml−1aluminum standard solution. The procedure proved to be suitable in terms of accuracy and selectivity for the microdosage of aluminum in mineral waters.
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