Structure of H2-NO2-Argon and H2-O2-Argon Laminar Prernixed Flames*
作者:
J. V. VOLPONI,
M. C. BRANCH,
期刊:
Combustion Science and Technology
(Taylor Available online 1995)
卷期:
Volume 105,
issue 4-6
页码: 195-209
ISSN:0010-2202
年代: 1995
DOI:10.1080/00102209508907750
出版商: Taylor & Francis Group
关键词: Combustion chemistry;flame studies;fuel-NOx;modeling;mass spectrometry;laser-induced fluorescence
数据来源: Taylor
摘要:
Measurements of the composition of stable and unstable species and temperature in laminar, premixed, flat flames of H2-NO2-Ar have been made and compared to the structure calculated with a flame code including detailed chemical kinetics. No previous detailed flame structure measurements and chemical kinetic modeling of this flame have been presented. Similar measurements and calculations are reported for a companion H2-O2-Ar flame in order to provide a comparison to a previously well characterized flame. Measurements were made of stable species concentration by probe sampling and mass spectrometric sample analysis. Measurements of relative OH concentration and of temperature were made by laser-induced fluorescence. Agreement between the measurements and calculations of stable species concentrations in the H2-NO2-Ar flame using existing chemical kinetic mechanisms with no adjustments to the kinetic parameters is discussed. The reaction mechanism is dominated by the three elementary reaction steps given below:
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