Thiol-s-triazine as a Stabilizer for Thermal Discoloration
作者:
Y. Nakamura,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1978)
卷期:
Volume 12,
issue 2
页码: 323-326
ISSN:0022-233X
年代: 1978
DOI:10.1080/00222337808061380
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The formation of longer polyene chains (thermal discoloration) has been found to be avoidable by using thiol-s-triazines, such as 2-anilino-4,6-dithiol-s-triazine (AF), which hardly reacts with the original chlorine atoms but tends to replace the activated chlorine (allylic chloride) that plays an important role in triggering zipperlike dehydrochlorination. The optimum stabiliizing system is: PVC, 100; DOP, 50; AF, 0.18; Zn stearate, 0.5; Ba stearate, 1.5 parts.
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