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Two-stage model for molecular orientational relaxation in liquid crystals

 

作者: I. Dozov,   S. Temkin,   N. Kirov,  

 

期刊: Liquid Crystals  (Taylor Available online 1990)
卷期: Volume 8, issue 5  

页码: 727-738

 

ISSN:0267-8292

 

年代: 1990

 

DOI:10.1080/02678299008047384

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The molecular reorientation in anisotropic fluids is considered as twostage process—fast single molecule rotation in the volume restricted by close neighbours and slow collective relaxation of the local surrounding. The theoretical results are applied to explain the discrepancy between the rotational diffusion coefficients D⊥robtained by infrared bandshape analysis and polarized fluorescence techniques.

 

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