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Is There an Ideal Crystal?

 

作者: E. Roland Dobbs,  

 

期刊: American Journal of Physics  (AIP Available online 1960)
卷期: Volume 28, issue 3  

页码: 243-249

 

ISSN:0002-9505

 

年代: 1960

 

DOI:10.1119/1.1935108

 

出版商: American Association of Physics Teachers

 

数据来源: AIP

 

摘要:

An elementary classification of crystals according to their binding forces shows that an ideal crystal, defined as a perfect lattice of spherical atoms held together with two-body, central forces, should be found among the inert gas solids. The calculation of a lattice energy from an interatomic potential of the Mie-Lennard-Jones form is discussed, and the results for the hexagonal and cubic close-packed lattices compared. For argon, it is shown that a (12,6) interatomic potential, whose constants have been calculated from the crystal parameters at 0°K, can be used to predict both the specific heat of the crystal and the second virial co-efficient of the gas over suitable ranges of temperature. A comparison of this interatomic potential with existing calculations of the interaction of two argon atoms shows that the macroscopic properties of argon can be calculated at present from a pair potential, but not directly from the properties of an argon atom.

 

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