Preparation of 3‐Aryl‐4‐(5‐ARYL‐Δ2‐1,2,4‐Oxadiazolin‐3‐YL)Sydnones and their Conversion into 3‐ARYL‐4‐(5‐ARYL‐1,2,4‐Oxadiazol‐3‐YL)Sydnones
作者:
Mou‐Yung Yeh,
Hsien‐Ju Tien,
Toshio Fuchigami,
Tsutomu Nonaka,
期刊:
Journal of the Chinese Chemical Society
(WILEY Available online 1986)
卷期:
Volume 33,
issue 1
页码: 61-71
ISSN:0009-4536
年代: 1986
DOI:10.1002/jccs.198600008
出版商: WILEY‐VCH Verlag
关键词: 3‐Aryl‐4‐(5‐aryl‐Δ2‐1,2,4‐oxadiazolin‐3‐yl)sydnones;3‐aryl‐4‐(5‐aryl‐1,2,4‐oxadiazol‐3‐yl)sydnones;3‐arylsydnone‐4‐carbonitrile oxides
数据来源: WILEY
摘要:
Abstract3‐Aryl‐4‐(5‐aryl‐Δ2‐1,2,4‐oxadiazolin‐3‐yl)sydnones (5) were synthesized in high yields by the reaction of 3‐arylsydnone‐4‐carboxamide oximes (prepared from the corresponding 3‐arylsydnone‐4‐carbonitriles) with aromatic aldehydes in the presence of acid catalysts. No reaction occurred when aliphatic aldehydes were used. The oxadiazolin‐3‐ylsydnones (5) were easily converted into the corresponding 3‐aryl‐4‐(5‐aryl‐1,2,4‐oxadiazol‐3‐yl)sydnones byN‐bromosuccinimide oxidation. The 3‐arylsydnone‐4‐carbonitrile oxides were synthesized in good yields byN‐bromosuccinimide oxidatio
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