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Short Syntheses Of (±)-6-Desoxy-6-Nitrodaunomycinone And (±)-11-Amino-6, 11-Didesoxy-6-Nitrodaunomycinone

 

作者: Xiaoping Fu,   JamesT. Pechacek,   DarrylL. Smith,   DesmondM.S. Wheeler,  

 

期刊: Natural Product Letters  （Taylor Available online 1992）
卷期: Volume 1, issue 3  

页码: 213-216

 

ISSN:1057-5634

 

年代: 1992

 

DOI:10.1080/10575639208048914

 

出版商: Taylor & Francis Group

 

关键词: 6,11-Substituted Daunomycinones;Can/Ddq(Cat)

 

数据来源: Taylor

 

摘要:

6-Desoxy-6-Nitrodaunomycinone (1b), Daunomycinone (1f) And The Novel (±)-11-Amino-6,11-Didesoxy-6-Nitrodaunomycinone (1g) Have Been Synthesized In 7,8 And 8 Steps Respectively From The Dihydroxy Ester (3a); The Addition Of Nitromethane To (3a) Works Efficiently Only When The Hydroxyls Are Equatorial.

 

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